ricinoleic acid soap
Oils considerably high in linoleic acid tend to have short shelf lives, and are usually referred to as “luxury oils”. For example, every time she tried to improve the recipe’s conditioning properties, it always led to a sacrifice in hardness. Hence the reason for the recipe’s 5% superfat and 30% coconut oil. ... Zinc Ricinoleate is a zinc salt of Ricinoleic Acid (q.v.). Body Firming Lotion. Previous posts dealt with lauric, myristic, palmitic and stearic acids. Ricinoleic acid is different from the other three unsaturated fatty acids because it has an OH (hydroxyl) group which increases the solubility of soap. This is where understanding the properties of each oil within a recipe (And most importantly, fatty acids. Each possesses its own unique blend. Anti Aging. Many soap makers believe that a sum higher than 15% significantly increases the likelihood of one’s soaps developing “DOS”, or “Dreaded Orange Spots”. In the email this very sweet crafter sent me, I was politely asked if I might offer help in formulating a soap recipe, or if I wouldn’t mind taking a look at a recipe this crafter had formulated herself. But why is this exactly? My very first question back was a kind inquiry as to the reason why this recipe needed to be both vegan and palm-free. Myristic Acid is a saturated fatty acid. Below is our Fatty Acid Profile Chart. It contributes to moisturizing and conditioning properties. 100% shea butter soaps are extremely conditioning, with more compact, low-lying lather similar to that of castile (100% olive oil) soap. In fact, around 90% of castor oil is ricinoleic. She was new to soap making and was hoping to formulate her own palm-free, vegan soap recipe. Each brings certain properties to the process of soapmaking and the finished product. It also contributes to bar hardness, cleansing and lather. Soap #3 … My biggest hope for all crafters though, whether your talents are completely new to you, or you’ve been improving them for years, is that when you do ask questions, the answers are always easy to find and even easier to put into practice... Not because someone handed you a fish though, but because someone amazing took you under their wing and taught you how to fish! The fatty acids we consider in soap making are: lauric, myristic, palmitic, stearic, ricinoleic, oleic, linoleic and linolenic acids. That’s absolutely okay though... Palmitic acid can range anywhere from 4%, all the way up to 20% and yield a great bar of soap! That alone is enough to make it fascinating; but what it does for soap is also interesting. Within a recipe, you’ll find that your saturated fats, or “hard oils”, will be higher in lauric, myristic, palmitic and stearic acids. BB Cream. So many of my fellow soap-aholics did that very same thing for me, and I will always be so eternally grateful to them! The palm-free, vegan soap recipe that I suggested to this kind crafter, based on the properties she desired most in her soaps (Hardness, conditioning and lather.) As the reference “soft oils” implies, these are fats which, among other things, generally contribute to the moisturizing/conditioning properties of a soap recipe. The values serves as backbone in determining the corresponding hardness, cleansing, creamy, bubbly, silky, longevity, comedogenic, and other related values on soap … Mica and Color - How to Label Colors, How Mica is Made, and More. Oleic Acid is an unsaturated fatty acid which conditions and moisturizes. It all goes back to the fact that while SoapCalc is an absolutely wonderful tool and guide for soap makers, it most certainly isn’t the “soap making Bible”. So, what did this particular recipe look like? Of course, you’ll also find high amounts of oleic acid in high oleic sunflower and canola oils. This fatty acid is prominent in castor oil and is great for adding a luxurious lather to the finished … Ricinoleic acid traces quickly and creates a hard bar of conditioning soap. Palm oil, lard, tallow and cocoa butter are all high in palmitic acid. Just as handmade soaps are as personal to the crafter as the craft is itself, so too are the ingredients in which we all freely choose to use and share with our friends, family and customers, by way of our incredible talent! The only oil that’s readily available to most … A recipe with as little as 3% stearic acid, all the way up to 15% stearic acid, will still yield a great bar of soap! The second combination of oils was 90% palm oil and 10% castor oil. In truth, you would probably dislike castor oil in a single oil bar. The sky’s the limit when it comes to formulating recipes! Castor oil is a vegetable oil pressed from castor beans. What does it do for soap? Please create account through ##customer_email## email. to the 48 contiguous United States of America. It’s no surprise that that’s where the olive oil in this recipe comes into play! Certainly, one of the biggest factors is cost (You can make a positively fantastic, outstandingly skin-loving bar of soap without breaking the bank on expensive butters and luxury oils! Soap made with soft oils, especially olive oil, is slower to trace and setup. I’m talking about my saturated to unsaturated fats ratio. We never keep payment information. Usually, our goal is to make a bar well-balanced for bathing, and it is the reason we mix oils rather than using just one oil. Your freedom of choice is a beautiful thing! It is an unsaturated omega-9 fatty acid and a hydroxy acid. Ricinoleic acid – structure (Source – PubChem) Ricinoleic Acid. Guest post by Amber Beltran of A Squirrel & A Scholar Soap Co. Join Amber's Facebook Group Soap Artistry and High-Top Soap Making For More Tips, Tricks, and Info. • The oil extracted from Soap A contained 4% ricinoleic acid. The coconut oil in our recipe is high in lauric acid. This is especially helpful to know when it comes to making substitutions in your recipes. Makeup Remover. Ricinoleic Acid will add conditioning properties, a fluffy lather and some creamy/stable lather! Ricinoleic Acid is an unsaturated fatty acid which offers conditioning, moisturizing, and lather-stability properties to a soap recipe. ), it would be in formulating a recipe which remains at, or very close to, a saturated to unsaturated fats ratio of 40:60. Getting to know this fellow crafter was an absolute pleasure (And I hope she’s reading this now so she knows just how grateful I am for her inspiration!). Teach him how to fish and you feed him for a lifetime”. The fatty acids we are concerned with for soap making are: lauric, myristic, palmitic, stearic, ricinoleic, oleic, linoleic and linolenic acids. When she tried to improve the recipe’s lather, its conditioning properties took a nosedive. It is, in my opinion, a fine recipe with the addition of sodium lactate for hardness. It is sometimes added to Turkey red oil and dry-cleaning soaps. A recipe’s unsaturated fats, or “soft oils”, will be higher in ricinoleic, oleic, linoleic and linolenic acids. Ricinoleic acid is perhaps the most interesting acid of all because of the oils, it is only found in castor oil. Far more important to me than that INS number down in the lower left of my computer screen are those numbers in the upper right. ... 90% ricinoleic acid… Ricinoleic acid seems to be one of great personal preference, as how much castor oil one incorporates into a recipe directly affects the ricinoleic acid content. This experience reminded me of a lesson I wanted to share as well: The answers to your questions are always out there- somewhere. Let’s take a look at each one of these, and the roles they play within soap recipes! If you have not tried castor oil in CP or HP soap, you may want to for your next batch. Toners/Astringents. Too much lauric acid can be drying, but this can be counteracted by reducing the percentage of coconut oil, increasing the recipe’s superfat, or balancing it with other fatty acids known for their moisturizing capabilities. Stearic Acid is yet another saturated fatty acid which contributes to hardness and a nice, stable lather. It not … In a bar at even a small percentage however, it is a team player, adding the aforementioned qualities, whether used at 2% or up to 25% in special circumstances. Fatty Acid … As if that was not enough, it also creates creamy lather. Be it through the help of social media groups dedicated to helping new soap makers to grow, an informative online article or blog (Hopefully this one included! The only oil that’s readily available to most soap makers which you’ll find to be high in ricinoleic acid is castor oil. Manufacturers and suppliers of a variety of industrial chemicals like Castor Oil Derivatives, Hydrogenated Castor Oil, 12 Hydroxy Stearic Acid, Ricinoleic Acid - Oil Base India ), I just wanted to make sure that her desire to create a vegan, palm-free soap recipe wasn’t based upon guilt or shame. I didn’t just want to give this dear crafter a recipe she could use for a day, I wanted to explain to her exactly why I formulated the recipe the way I did so she could expand upon it, change it, improve it, and make it her own for a lifetime! Soap #2 has a 38:62 ratio. In formulating a recipe that was both palm-free and vegan, I turned to shea butter! Let’s take a look! Lauric Acid is a saturated fatty acid. Rice Bran Oil 26 1 69 1 25 0.128/0.179 Composed of the following fatty acids: Myristic- 1% Palmitic- 22% Stearic- 3% Oleic- 43% Linoleic- 26% Rice bran oil provides conditioning, rich, … I suggested a superfat of 5%, and a lye concentration of 33%. The lanthanum ricinoleate can be synthesized by the reaction of ricinoleic acid, lanthanum nitrate and sodium hydroxide. After corresponding with this fellow soap maker more, I came to know that she herself was vegan, and that by personal preference alone, she preferred to use recipes which were palm-free as well. For this particular recipe, this is where that 30% coconut oil and 10% castor oil come into play! The Ruchi Group, established in early 1970s, is one of the top Indian conglomerates with a proven track record in the field of Edible Oils, Health Foods, Dairy, Steel, Pharmaceuticals and … Lends a quick foaming and rich texture to soap fomulas, as well as a great moisturiser for soap. A palm-free, vegan recipe, such as this, will be considerably lower in palmitic acid, especially since we haven’t included any cocoa butter. Most soapmakers calculate well under 10% however, for a general bath bar. Precautions : Keep out of streams, rivers and lakes. On a personal level, I absolutely love recipes with lots of castor oil, and it shows in this particular recipe’s high ricinoleic acid content of 9%. Not that there is anything wrong with a recipe such as this by any stretch of the imagination (And in fact, the very soaps I sell myself are without animal by-products. It doesn’t require much to enjoy the skin-loving benefits shea provides! However, its main use is as chemical intermediate to … But why shea exactly? The oral administration of ricinoleic acid (10 mL) induced alterations in digestive patterns that were qualitatively similar to those induced by the intraduodenal administration of sdium … Just as this reference implies, hard oils, among other things, help to contribute to the hardness of your soap. Pore Strips. Nourishing; After Sun Product. They’re the fats within your recipe which are typically solid at room temperature (Unless you live in Florida and your coconut oil is only solid for 2 months out of the whole year!). Castor oil has a similar effect on the … Abide by all laws per this regulation. Many soap makers feel that recipes containing more than 25% coconut oil can be drying to the skin unless counteracted by an increase in superfat (Extra oils added to one’s recipe for the purpose of remaining “free floating” within the soap.). Even when life get so busy that I’m not always able to reply as quickly as I wish I could, I value and appreciate you all so incredibly much... You keep me going and inspire me in so many ways! It can contain anywhere from 4% to 11% unsaponifiables (Components within the butter that cannot bond with a lye molecule to become soap.). In this case, the unsaturated ricinoleic acid … Soaps high in shea butter make awesome bars to use during the winter! Butters are high in stearic acid, and we’ll find a high amount of it in this recipe from the shea butter. None of the other oils contain it at all. We take advantage of the properties of each oil to create that ideal bar. Exceptions to this are not uncommon, but this is typical. It goes something along the lines of, “Give a man a fish and you feed him for a day. Fats and oils are made up of fatty acids. In a recipe such as the palm-free, vegan one we’ll be discussing here, without the addition of hard oils, such as lard, tallow, palm oil, etc., the result can be a rather softer bar of soap. A more commonly recommended usage rate for shea butter within a soap recipe falls typically within the 5% to 15% range. Join us for our next fatty acid review, oleic acid. Once ricinoleic acid binds to these receptors, it causes those muscles to contract and push out stool, just as other stimulant laxatives do. A recipe with a balanced saturated to unsaturated fats ratio makes for a wonderfully balanced bar of soap! To understand your fatty acids in soap making (And as such, understand the properties of your oils/fats/butters.) If you think back to the information about the Cleansing number, you may realize you will have to balance your love of bubbles created by lauric and myristic acid against the harshness of soap … Safety Data Sheet . I’ve received emails of gratitude, messages from fellow crafters with excellent questions, and such sweet compliments which have left me feeling truly flattered and so thankful to be a part of this amazing crafting community! If I had my way, “INS” would stand for “It’s Nothing to Sweat”, or “It’s Not a deal breaker, Seriously!” I’ve made soap batches that have stayed within every recommended usage rate for the fats I incorporated into my recipe, and had perfect INS scores of 160 that I didn’t enjoy nearly as much as batches which pushed the boundaries, and had less-than-perfect INS numbers... Really! Regardless of more commonly used rates though, there’s really no maximum amount you can use in your recipes. This is a great recipe which makes for a fantastic soap frosting recipe too, but it’s also very customizable! Well, it contributes to hardness, cleansing and lather. 8 Ricinoleic acid, potassium salt 9 Nonanoic acid, ammonium salt 10 11 Other Name: 12 Potassium salts of fatty acids 13 Ammonium salts of fatty acids 14 15 ... Fatty acids and soap salts—such as nonanoic acid … Until next time, may your days be filled with bubbles and wax. You have more time to color and play with the soap batter. Ricinoleic acid is used in pigment, printing ink, and textile finishing. In fact, a high stearic acid content will help make up for the lower palmitic acid content found within many palm-free, vegan recipes. This makes them perfect for swirling. 137 Together with pentaerythritol (3 parts per 1 part of soap) it forms a … I really do live for the opportunity of being able to show you, my fellow, amazing crafters, all the wonderful things that can be created using Nurture Soap’s phenomenal products! It not only Shea butter is cold-pressed from the seeds of the Karite tree and is wonderfully moisturizing! Well, butters can be a bit pricey, and some are just downright expensive! Again, the coconut oil in our recipe contributes to the myristic acid content, but a good replacement for it can be found in Babassu oil, which also contains a good amount of myristic acid. Soap #1 has a 36:64 ratio, which made its hardness marginal. In this particular recipe, the sum of the linoleic and linolenic acids is 7%. Of course, I was incredibly honored that she’d reach out to me for help, and I was more than delighted to do just that, but there’s also this old proverb that I firmly believe in too! The highest honor I’ve received since being given this awesome opportunity to write guest blogs for Nurture Soap is in the messages I’ve received! 6.3 … THANK YOU!! Well, butters are what are commonly referred to as “hard oils”. is to hold the key to always being able to easily formulate your best, most loved soap recipes! … So, for the sake of simplifying things, let’s back up here for a moment and talk about that infamous INS number. Each brings certain properties to the process of soapmaking and the finished product. are substituted with soft oils. Oil fatty acid table summarizes the fatty acid profile used in My Soap Calc™. Call or write us with any questions. Ricinoleic Acid is an unsaturated fatty acid which offers conditioning, moisturizing, and lather-stability properties to a soap recipe. That alone is enough to make it fascinating; but what it does for soap is also interesting. Additionally, its viscosity helps to stabilize lather and assists oils high in myristic and lauric fatty acids create more, bigger bubbles. One would simply need to remain aware of the properties shea butter imparts in soap, and the outcome it would produce at higher percentages. Take you fatty acid ratios and profiles to heart more, and you’ll always end up with recipes that you love... That’s what matters most! Again, you’ll find many palm-free, vegan recipes to be higher in stearic acid and lower in palmitic acid. Around Eye Cream. Ricinoleic is only found in … We will discuss one fatty acid per post. We never test on animals and our suppliers don't either. Common unsaturated fatty acids used in soap-making are oleic acid, linoleic acid, alpha- and gamma-linolenic acid (these are also known as omega fatty acids – again, something you may have come across before in the context of nutrition), and ricinoleic acid. ), and the other is my fatty acids. • The original oil contained 9% ricinoleic acid. Here’s what this recipe looks like when plugged into SoapCalc: Remember, when plugging your own formulations into SoapCalc, don’t worry if your recipes fall short of that “magical” INS number of 160. Its boiling point is 313 °C (595 °F) and its density is 0.961 g/cm 3. This week’s blog topic was inspired by a truly wonderful fellow soap maker who recently reached out to me in an email. The resulting soap contained a higher-than-expected concentration of unsaturated oil, regardless of whether the olive oil was added at trace. Castor oil is a colourless to very pale yellow liquid with a distinct taste and odor. It’s just that when a kindred soap maker came to me for advice and help, not only was I happy to do so, I was also incredibly honored! consisted of 40% olive oil, 30% coconut oil, 20% shea butter and 10% castor oil. You're safe with us! Again, you’ll find many luxury oils to be high in linolenic acid, but it’s also present in small amounts in more well-known, commonly-used oils too, such as rice bran oil, sunflower oil and olive oil. Impressive Anti-Inflammatory Effects. It includes a mixture of triglycerides in which approximately 90 percent of fatty acid … Her biggest dilemma in formulating such a recipe though was that of cost and the properties of the soap itself. To every single crafter who has reached out to me, I want you to know that in every way, you brighten my days and are a true gift to me! She was stuck in what I like to call “SoapCalc hell”! No matter where you are in the process or soap making ie a newbie or experienced soap maker, it’s important for you to understand which what properties soap making oils have so you can make the best soap possible with the oils you have on hand. I firmly believe that no soap maker on the face of this planet should ever be made to feel shamed for the ingredients they choose to incorporate into their handmade soaps. Ricinoleic acid traces quickly and creates a hard bar of conditioning soap. After all, conditioning is great, but most soap makers want to produce soaps which are nice and hard, cleansing to the skin, have beautiful, bubbly lather, and a lovely creaminess too. [3H]Ricinoleic acid (5%) mixtures were prepared in water containing either 5% mineral oil or 5% PEG 200. Previous posts dealt with lauric, myristic, palmitic, stearic and ricinoleic … Mixture is regulated as oil under the Clean Water Act. When I formulate recipes, I do so with a few factors in mind, which have far more importance to me than hitting that soapy “bullseye” of 160. Mask. Linoleic Acid is an unsaturated fatty acid which conditions and moisturizes, as well as adds a silky-soft lather. Hello my magnificent masters of suds! Many soap makers prefer to keep their usage rate of castor oil at, or below, 5%. Knowing your fatty acid profiles can help you better formulate and substitute oils. We'll be glad to help! High in Ricinoleic acid, low levels of Oleic, Palmitic and Stearic acids. Indeed, I feel that a lot of new soap makers can become easily discouraged by SoapCalc, especially when it’s been drilled into the mind that the “perfect” soap recipe has an INS number of 160. Linolenic Acid is an unsaturated fatty acid. Ricinoleic Acid is a fatty acid that comprises up to 90% of the oil extracted from the Ricinus Communis or castor oil … CA0154 Ricinoleic Acid . In the world of butters, shea butter is a much more affordable option, and it just so happens to be super skin-loving too! Please feel free to enjoy it in your own soap making adventures, or tailor it to make it uniquely yours! Based on affordable, skin-loving oils/fats, and the fatty acid profile of each one in consideration of the properties desired in the finished soap, I was honored to help a fellow soap maker begin her own formulating journey! “INS” stands for... Well, no one really knows with 100% certainty actually! Castor Oil maintains its fluidity at both extremely high and low temperatures. Beyond lye safety, there are no “rules” in soap making, only guidelines and recommendations. The higher percentage of shea butter will produce a delightfully conditioning bar of soap, while the coconut and castor oils will help to increase and sustain lather which the shea butter may hinder. Palmitic Acid is a saturated fatty acid which contributes to hardness, creaminess and a stable lather. You can view your wishlist by creating or logging in to your account. moisturizes, but is hygroscopic, meaning it draws moisture. She went on to explain that every time she made an improvement to the formulation in one area, it meant a sacrifice in another. It is a major component of the seed oil … A bar that is hard and long-lasting, but lathers well and cleans without drying the skin is the goal for most batches. The properties of these fatty acids are exactly why I formulated this palm-free, vegan recipe the way I did. ), make their entrance! Shea butter steps in to help increase some of the hardness lost due to not incorporating these certain fats. Liquid Hand Soap. It makes a thick, tacky, “lather” on its own that is rather unpleasant. To make it even more frustrating, there’s all these other numbers which pop up when you hit that “Calculate Recipe” button, and that can really make things feel a bit overwhelming! Ninety percent of the fatty acids in Castor Oil are ricinoleic acid which is a monounsaturated, 18-carbon fatty acid. For example, shea butter won’t contribute much to abundant lather, but what it lacks in copious lather, it makes up for in its conditioning, moisturizing, emollient and humectant properties. The short shelf life of oils high in linolenic acid is precisely why many seasoned soap makers prefer to keep the sum of their linoleic and linolenic acids within their recipes below 15%. With the unsaponifiable components within the shea butter in this recipe, you can be rest assured it’ll help to keep the soap nice and conditioning! ), or even newfound friends with shared interests; the answers are usually just around the corner, waiting for the questions to be asked! What’s not to like? • The oil extracted from Soap B contained 4% ricinoleic acid. So far, we’ve got a palm-free, vegan soap recipe that is wonderfully conditioning, due to lots of shea butter, but how does one formulate a soap recipe that won’t break the bank, contains simple and accessible ingredients, and produces a balanced bar of soap? 0.1286: Cherry Kernel oil: Fantastic in conditioning bars, but should be used with other oils and butters to produce a harder soap… But what did all this mean for my friend and fellow crafter looking for help in formulating a nice, balanced, skin-loving, palm-free, vegan soap recipe? CURRENT PROCESSING TIME IS 3 BUSINESS DAYS. Evening primrose oil, hemp seed oil, carrot seed oil and rosehip seed oil, etc., are all high in linoleic acid. The biggest surprise of all is that this soap makes not one bubble! This is why these popular soap making oils make great substitutes for some, or all, of the olive oil within a recipe. As a general guideline, hard oils are substituted with hard oils, and soft oils (Fats which are liquid at room temperature.) Other (3H)Ricinoleic acid mixtures were formulated with the following three … Ricinoleic acid, the main fatty acid found in castor oil, …
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